Waxer and Boil first appeared in Season 1 Episode 20 "Innocents of Ryloth" (which is part 2 out of the 3-part Ryloth trilogy)
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winx club season 5 episode 14 when come out
Season 5 episode 3
season4 episode 8
I don't think it will come out
There is no Season 2 Episode 26. Episode 25 was the season finale.