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Going by the US version of Naruto Shippuden, Sai is introduced in episode 33 of season 1 when Danzo gives him his mission. Naruto meets Sai when he is searching for a third team mate to fill the gap in Team Kakashi. Naruto, Shikamaru, and Choji fight against Sai but he easily disappears before naruto even lands a blow. It is after this first encounter in episode 34 that Naruto learns that Sai will be Sasuke's replacement with the addition of a substitute captain code named Yamato, a member of the Anbu Black Ops Division.

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14y ago

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That is the fuma clan filler arc, part 1 episodes 136-141.

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12y ago
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episode 32

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14y ago
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