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Order 66 was the codename for the command that all the Clone Troopers should immediately turn on their Jedi commanders and kill them. Palpatine gave the order and told the Clone Commanders it was because the Jedi were exacting their plot to take control of the Republic, but it was actually Palpatine that was taking control.
Lord (Darth) Sidious
Surprisingly, yes. He was also a debatably better duelist, but was not as powerful with the force.
Agen Kolar dies because when mace windu and fellow jedi including Agen Kolar go to arrest chancellor Palpatine, palpatine stabs his lightsaber through Agen Kolar's stomach.
Saesee Tiin dies because when Mace Windu and fellow jedi including Saesee Tiin go to arrest chancellor palpatine, palpatine stabs him in the neck after stabbing Agen kolar in the stomach.