if your talking about the impure world resurrection, the episode hasn't been made yet, its only happened in the manga
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Episode 77 to 79 :)
yes, he kills him in episode 68
on shippuden, shikamaru defeats hidan on episode 87 or around that.
In Naruto Shippuden episode 56. Title: Writhe
Asuma did not get married. He was in a relationship with Kurenai, and she was pregnant with his child. However, Asuma was killed before the baby was born.