Yes, there was such a villain. Simlar to the Riddler, the Puzzler left puzzle clues. His only film or TV appearance was in the 1960's Batman TV series.
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In the original edition of the Batman comic, the very first book ever released contained the Joker. The Joker was the first villain that Batman ever defeated.
It belongs to a villain. Youll find out who when you complete the side quest
The nominal villain is the Scarecrow, actually Arkham psychologist Jonathan Crane (Cillian Murphy), who plots with Ra's Al-Ghul to poison Gotham's water supply.The true villain is revealed to be "Henri Ducard" (Liam Neeson) who trained Bruce Wayne to be Batman, and is actually the mastermind Ras Al-Ghul.*Another minor villain is serial killer Victor Zasz (originally Zsasz in comics), as one of Carmine Falcone's thugs who menaces Rachel and a child in one scene.