Not really; Pain, or actually the six paths of pain, is a technique that Nagato uses through six bodies.
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Nagato, who is the one true Pain, wore the headband of Amegakure.
Nagato is the real Pain on Naruto. Nagato si Jiraiya's first well apprentice is how I'm gonna put it, he's the real Pain it reveals that in book 47 or 48 I think.
You find out in one manga that one of the Akatsuki members (Tobi if memory serves right) had talked about Nagato (Pain) and had said "Who would've guessed that the Uzumaki's trademarked red hair has been used so much it turned snow white?". Because, remember? Pain had orange hair, yet Nagato (the real pain) had red hair!
In truth, no one died. After naruto talks to Nagato, Nagato preforms one last Jutsu before he dies. It revives everyone in the village who died fighting in that Pein battle.
Pain's real name is nagato