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Season 11 episode 14. It's on disc 3 and it's called "Alone Again, Natura-Diddily"


His first wife, Maude, died in a freak t-shirt toss accident in Season 12's Alone Again, Natura-Diddily..

His second wife, Edna, died off screen but was never directly stated she died, however the first direct implication she was dead was an extra scene at the end of The Man Who Grew Too Much from Season 25.

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Q: In which Simpsons episode does Maude Flanders die?
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