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Piper and Leo tried to marry 2 times first in "Magic Hour". They are caught by the elders though and Leo is taken away. The elders allow him to come back in the episode "Once upon a time" this time they are allow to marry if they can proof their relationship is strong enough to survive. Finally, they really marry in Just Harried.

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Q: In what episode of charmed does Piper marry Leo?
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