Episode, 105 (Original Naruto, Not Shippuden)
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Naruto end of episode 56 and start of episode 57
She died by falling of a cliff
actually its episode 331 "All Torkoal, No Play"
The episode in which they kidnap him and turn him into a boy joker then batman has to save him but robin accidentally kills the joker trying to aim at b man and Harley also dies falling from a cliff and batgirl fails to save her the end that was a lot of writing