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He doesn't. Even if he wanted to he couldn't.

What the Akatsuki want is the 9 tailed beast (a.k.a. Naruto..) for Tobi (a.k.a. Madara, a.k.a. Obito) to have the moon eye.

So, no. There is no episode where Naruto joins the Akatsuki.

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2010-05-07 22:42:44
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Q: In what episode does Naruto join the Akatsuki?
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