She was born in 1972 and Charmed started in 1998 so she was 26 years old.
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The first episode of Season Four. I believe it was called Charmed Again.
Leo's first appearance in Charmed was in the first season, episode 3. It's called 'thank you for not morphing.'
the first episode of season 4
It is in season 3 first episode. Honeymoon's over.
she first appeared in charmed again part 1 season 4 episode 1