you cant there is only 18 characters and the rest of cool characters people say is a lie like nine-tails and pain as well
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Naruto becomes a hero in shippuden by killing several Akatsuki members including their main member Pain.
Naruto Shippuuden does not have "Seasons". It has Sagas (like all Anime series') The Saga in which Naruto defeats Pain is called the "Pain Invasion Arc".
Nagato, who is the one true Pain, wore the headband of Amegakure.
He joins akatsuki in Naruto shippuden episode 142
Chapters 430 to like 444. The way the chapters are im guessing that it how much is about Naruto vs. Pain.