You can get it from www.clickdvdmedia.com
They offer DVDs of public domain TV shows. In other words, copies of the shows that haven't been released on DVD yet. Not sure of the quality or shipping time but if you must have something, seems they would be worth a try.
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five seasons
there are five...
You can watch the entire series on http://thementalistonline.com/en/
They haven't even started shooting the third season. There will probably be 13 episodes, same as the first two seasons.
The original Dark Shadows was not split into seasons. However, there were 1,225 episodes. It was in black and white from 1966 to 1967. It was colorized in 1967, and it then ran from 1967 to 1971.