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Enthalpy is the amount of energy in a system and when this changes (when a reaction happens), the energy is either released (exothermic) or absorbed (endothermic) and this energy is usually released or absorbed as heat. Therefore when the enthalpy decreases, heat is released from the system making it exothermic. In contrast, when the enthalpy increases, heat is absorbed making it endothermic.

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āˆ™ 15y ago
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āˆ™ 13y ago

Enthalpy of water (100% liquid, 0% steam) has a direct relation with pressure and temperature

Enthalpy of vaporisation (mixture of liquid and steam) has an inverse relation with pressure and temperature

Enthalpy of steam (100% steam, 0% liquid) at saturation has a direct relation with pressure and temperature

Enthalpy of super-heated steam (steam at a temperature above its saturation temperature) has a direct relation with temperature and an inverse relation with pressure

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āˆ™ 11y ago

enthalpy is a diffrence of reducing temperature. and temperature is a hotness or coldness of a product or a area.

The above answer can be re-state as:

Enthalpy is a measure of the total energy inside a thermodynamic system. (emphasize on thermodynamic because enthalpy and temperature in classical way are not defined beyond chemical equilibrium). There are actually two types of enthalpy but people don't usually make a difference: formation enthalpy and sensbile enthalpy. Sensible enthalpy is the one related to temperature. Sensible enthalpy is the energy change in the system as the temperature of the system is modified. Mathematically is expressed in terms of specific heat at p=const and temperature i.e.: h=cp*T (for calorically perfect gas only). The formation enthalpy is a different story has to do with the chemical energy of the molecule (sometimes this is also called heat of formation). Hope this helps!

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Q: What is the relationship between enthalpy and temperature?
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What is the relationship between the enthalpy h and entropy s of a reaction that is spontaneous at higher temperatures but not at lower temperatures?

The relationship between enthalpy (H) and entropy (S) is described by the Gibbs free energy equation, Ī”G = Ī”H - TĪ”S, where Ī”G is the change in Gibbs free energy, Ī”H is the change in enthalpy, T is the temperature in Kelvin, and Ī”S is the change in entropy. For a reaction to be spontaneous at higher temperatures but not at lower temperatures, the entropy term (TĪ”S) must dominate over the enthalpy term (Ī”H) in the Gibbs free energy equation. This suggests that the increase in entropy with temperature plays a more significant role in driving the reaction towards spontaneity than the enthalpy change.


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Gibbs energy accounts for both enthalpy (heat) and entropy (disorder) in a system. A reaction will be spontaneous if the Gibbs energy change is negative, which occurs when enthalpy is negative (exothermic) and/or entropy is positive (increased disorder). The relationship between Gibbs energy, enthalpy, and entropy is described by the equation Ī”G = Ī”H - TĪ”S, where T is temperature in Kelvin.


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