No... You should not use baking powder instead of baking soda because there is a different effect in the rising of what you are baking and it could possibly effect the taste depending on the thing you are baking/making.
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YES. Baking soda is cheaper & more effective to use.
I have a pool business in Va. & have been using baking soda in instead of P.H. increaser for years on salt & chlorine pools.P.H. increase & baking soda are basically the same thing. sodium carbonate/ sodium bicarbonate.
No. Check with a pool supply store to be sure. They will probably recommend pool acid.
Note: Be sure to use the correct acid, and in the correct amount. Again, a pool supply store can help with both of these considerations. baking soda is a alkaline salt, so it will have little effect. An acid is required to counter alkalinity.
If you mean baking soda for baking powder, or vice versa, then no, they act differently.