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The role of metastable states in circumventing laser pulse jitters in multi-step laser excitation of high-lying Rydberg and autoionizing states is discussed. A case study is presented where step-wise excitation of 3d4d (3)G(3,4,5) states of Ca is achieved despite a large jitter between the laser pulses

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Q: What is the role of metastable state in laser?
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