The reaction has to be carried out at neutral conditions because in acid the chromate indicator concentration decreases due to the reaction with the H+ ions, forming HCrO4-. It cannot be in too basic of a solution (greater than 10.5) because then silver hydroxide will form before the silver chromate can form.
When pH is lower than 7, chromic ion gets protonated and chromic acid is predominant in the solution. Consequently, if the pH is above 7, chromate ion concentration is too low to form precipitate with silver ions at the end point. If the pH is above 10, brownish silver hydroxide is formed masking the end point. hence a neutral medium must be maintained
For a reaction to be feasible for titration, it must be a quantitative reaction, meaning it goes to completion with a known stoichiometry. The reaction must also be fast enough to proceed to completion within a reasonable time frame. Additionally, the reaction should have a distinct endpoint to indicate completion.
to get rough volume....
Rinsing the titration flask with distilled water helps to remove any residue or impurities from the previous titration, which could affect the accuracy of the next titration. It ensures that the flask is clean and free of any substances that could interfere with the reaction being studied. This step is crucial for obtaining precise and reliable titration results.
To minimize the chance of side reactions, errors, or contamination from the surroundings. A slow titration could result in inaccurate results due to reactions with air or impurities. Rapid titration helps to ensure more precise and reliable measurements.
When pH is lower than 7, chromic ion gets protonated and chromic acid is predominant in the solution. Consequently, if the pH is above 7, chromate ion concentration is too low to form precipitate with silver ions at the end point. If the pH is above 10, brownish silver hydroxide is formed masking the end point. hence a neutral medium must be maintained
1- done only in neutral medium. 2- all the cations which give insolublld be chromate must be absent or removed before titration. 3-titration of Ag+ with Cl- is not feasible. 4- not suitable for I- and SCN-
I want to assmue the the readers of this answer have know the details theory and calculations about Mohr method if not u can refer to Any analytical text for reference. Well, Bromide and Chloride can not be determine simultaneously in a sample using Mohr method , the reason be that the indicator use for each of them is different. and there will be problem in the procedure if ones try to determine both simultaneously. To determine Chloride Ion, Ammonium or Potassium Thiocynate is used as indicator and the sample must be neutral or slightly acidic. while Eosin indicator is use for the determination of Bromide Ion and the same neutral solution is prefer for this purpose, the solution must be adjusted to neutral either by adding small amount of Nitric acid or by adding small amount of carbonate as the case maybe. But, in the determination of each of them Silver Nitrate is use for the titration of both and this is the similarity they shared and the experimental procedure is quite the same. Olajire Mojeed
For a reaction to be feasible for titration, it must be a quantitative reaction, meaning it goes to completion with a known stoichiometry. The reaction must also be fast enough to proceed to completion within a reasonable time frame. Additionally, the reaction should have a distinct endpoint to indicate completion.
to get rough volume....
It is not mandatory; acids are also titrated.
Rinsing the titration flask with distilled water helps to remove any residue or impurities from the previous titration, which could affect the accuracy of the next titration. It ensures that the flask is clean and free of any substances that could interfere with the reaction being studied. This step is crucial for obtaining precise and reliable titration results.
A neutral atom must contain an equal number of electrons because it is a neutral atom.
To minimize the chance of side reactions, errors, or contamination from the surroundings. A slow titration could result in inaccurate results due to reactions with air or impurities. Rapid titration helps to ensure more precise and reliable measurements.
Neutral must never be cut off.
Precision in the titration process is important for accurate determination of the end point. An indicator must change color very close to the equivalence point to provide a clear signal for the endpoint of the titration. If the indicator is not precise enough, it can lead to errors in determining the correct endpoint of the titration, affecting the accuracy of the results obtained.
To have a neutral atom, the atom must have the same amount of protons, neutrons, and electrons inside of it.