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This method uses a back titration with potassium thiocyanate to determine the concentration of chloride ions in a solution.
Before the titration an excess volume of a standardized silver nitrate solution is added to the solution containing chloride ions, forming a precipitate of silver chloride (AgCl). The term 'excess' is used as the moles of silver nitrate added are known to exceed the moles of sodium chloride present in the sample so that all the chloride ions present will react.
Ag+ + Cl- AgCl(s) (Ksp = 1.70 × 10−10)
Excess White
Excess of Ag+ is back titrated with SCN-.
What else can I help you with?
What is a volhard method?
It is an indirect titration procedure for the determination of anions that precipitate with silver like CL-, Br-, I-, SCN-, and it is preferred in acid (HNO3) solution (because it prevents the harmful effects seen in other methods in which oxalate, arsenate and carbonate are used. Because these ions form silver salts with poor solubility, but in acidic mediums these salts are not formed). A measured excess of AgNO3 is added to precipitate the anion, and the excess of Ag+ is determined by back titration with standard potassium thiocyanate solution.Dr. Sami
What is a back titration?
A back titration is a technique used in analytical chemistry to determine the concentration of an analyte by reacting it with an excess of a known reagent, then back-titrating the remaining excess reagent. This method is useful when the analyte reacts slowly or incompletely with the titrant in a direct titration.
What are the two indirect method of titration?
The two indirect methods of titration are back titration and reverse titration. In back titration, an excess of a reagent is added to react with the analyte, and then the unreacted excess is titrated to determine the amount that reacted with the analyte. In reverse titration, a standard solution is first added to a known amount of analyte to react completely, and then the excess standard solution is titrated back to determine the amount that reacted with the analyte.
What are complexometric titration method?
Complexometric titration is a type of volumetric analysis used to determine the concentration of metal ions in a solution by forming complexes with a specific reagent. In this method, a chelating agent is typically used to form a stable complex with the metal ion, and the endpoint of the titration is usually determined using a colorimetric indicator or a pH meter. This technique is commonly employed in the analysis of a variety of metal ions in solution.
Does it take more NaOH in back titration with phenolphthalein?
Yes, it takes more NaOH in a back titration with phenolphthalein compared to a direct titration because the indicator reacts with the excess acid in the sample before the endpoint is reached. This means more base is required to neutralize the excess acid present.
What is a volhard method?
It is an indirect titration procedure for the determination of anions that precipitate with silver like CL-, Br-, I-, SCN-, and it is preferred in acid (HNO3) solution (because it prevents the harmful effects seen in other methods in which oxalate, arsenate and carbonate are used. Because these ions form silver salts with poor solubility, but in acidic mediums these salts are not formed). A measured excess of AgNO3 is added to precipitate the anion, and the excess of Ag+ is determined by back titration with standard potassium thiocyanate solution.Dr. Sami
What is a back titration?
A back titration is a technique used in analytical chemistry to determine the concentration of an analyte by reacting it with an excess of a known reagent, then back-titrating the remaining excess reagent. This method is useful when the analyte reacts slowly or incompletely with the titrant in a direct titration.
What are the two indirect method of titration?
The two indirect methods of titration are back titration and reverse titration. In back titration, an excess of a reagent is added to react with the analyte, and then the unreacted excess is titrated to determine the amount that reacted with the analyte. In reverse titration, a standard solution is first added to a known amount of analyte to react completely, and then the excess standard solution is titrated back to determine the amount that reacted with the analyte.
What is the chemical process for back titration?
In back titration, a known excess of a reagent is added to react with the analyte. After the reaction is complete, the amount of excess reagent is determined by titration with another reagent. The difference between the initial amount of excess reagent and the amount required in the back titration is used to determine the amount of analyte present.
What are complexometric titration method?
Complexometric titration is a type of volumetric analysis used to determine the concentration of metal ions in a solution by forming complexes with a specific reagent. In this method, a chelating agent is typically used to form a stable complex with the metal ion, and the endpoint of the titration is usually determined using a colorimetric indicator or a pH meter. This technique is commonly employed in the analysis of a variety of metal ions in solution.
What is Back titration?
A back titration is a form of titraiton in which an excess of standard reagent is added and then the reverse of the titration is carried out.
Does it take more NaOH in back titration with phenolphthalein?
Yes, it takes more NaOH in a back titration with phenolphthalein compared to a direct titration because the indicator reacts with the excess acid in the sample before the endpoint is reached. This means more base is required to neutralize the excess acid present.
What difference between titration and back titration?
In fact, a back titration is carried out as in a very similar method to an ordinary titration. the only difference is in the context. Consider an unknown acid solution. Then a known amount of excess alkali was added to the solution and made them react. Then the process of finding the amount left from the alkali is known as the back titration.
When should back titration used instead of back titration?
when we do not know nothing about the other titrant.
Why do we usually use a back titration to determine nickel in steel?
Back titration is often used to determine nickel in steel because nickel can form stable complexes that make direct titration difficult. In a back titration, an excess of a reagent that reacts with nickel is added, and the unreacted excess is then titrated with another solution. This method allows for more accurate measurements by accounting for the complexities of the reaction and the presence of other elements in the steel matrix. Additionally, it minimizes interference from other metals that may be present.
Explain the technique of back titration?
Back titration is a technique used in analytical chemistry to determine the concentration of an analyte by reacting it with an excess of a known reagent, then back-titrating the unreacted excess with another reagent. This method is useful when direct titration is not feasible due to issues such as slow reaction kinetics or interference from impurities. By analyzing the amount of excess reagent that reacted, the initial concentration of the analyte can be calculated.
When to use back-titration instead of direct titration?
Back-titration is useful when the analyte reacts slowly or not at all with the indicator used in direct titration. It is also used when the endpoint of the direct titration is not clearly visible. Additionally, back-titration is employed when the analyte is present in very low concentrations and requires a larger amount of titrant for direct titration.
