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Chlorine and Fluorine generally do not react with each other, because they are in the same family, but they do form a highly reactive mixture. If the atoms happen to combine, I would assume you would get a Chlorine Monofluoride molecule, because chlorine and fluorine both have 7 valance eletrons, so they might share one, and it would look like this

Cl-F

they would share an electron, like F2, or Cl2 do.

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