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The very first practical automobile was built in Germany 1886 by Karl Benz. It was a 3 wheeled vehicle called the Benz Patent-Motorwagen. The MPG of this car is unknown.
http://en.wikipedia.org/wiki/Benz_Patent-Motorwagen
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Ford's 1908 Model T with a 2.9 liter 40 Horsepower, 45 mph top speed got 25mpg.
Benz patent Motorwagen also 25 mpg, 0.95 liter 1 cylinder