There is a really good article on the Today Money website from NBC News. It has 10 tips on how to donate a car to charity. The first step is to make sure there is no middle man. The more aggressively a charity advertises (i.e. their jingle on the radio or television ad nauseam), the more they pocket from your car than actually donate. Find a charity through Charity Navigator. Check to see if you will be eligible for a tax deduction. To save money, drop off the car yourself. These are just a few of the tips.
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