No, Naptha is not a strong enough solvent to remove wood stain from furniture. Use a paint and stain stripper instead. They are available in environmentally friendly versions along with versions that actually work.
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Naptha and mineral spirits will remove polishes and waxes but not oil based stains or coatings.
Very dark brown.
You will have to remove the old varnish in it and make its surface smooth with the use of a sand paper and refinish it with a lighter colored finish. You may use Linoleum for that as they are good for polishing the outdoor furniture.
For a seamless finish, apply the stain before assembling the furniture.
Primers are good for protecting against stains, wood sealer is good for soft woods, and wood stains are good for different types of wood. Semitransparent stains are meant for bare wood and semisolid is meant for ones that have previously been stained.
A espresso finish is a very dark brown that's almost black but not quite. it looks like a very dark cup of coffee with a little creamer or milk in it pretty nice in the right setup.