painting of oil is called oil paint and painting of vinyl is called vinyl paint
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It makes a difference if you are putting it on a deck, as you suggest. Oil paint may not survive more than a year on an outdooor deck.
one used oil paint and the other used water colours
In the past oil paints referred to either petroleum based paints or linseed based paints. Today in the USA petroleum based paints are no longer sold and it is difficult to find linseed based paints though they do exist with a small proportion of linseed oil. Alkyd paints are made with synthetic oil and are readily available and have come to be known as "oil" paint.
No, it won't stick very well. However, a 100% acrylic paint will adhere very well to vinyl siding. Just insure that the paint you are using is no darker than the original color of the vinyl siding to avoid warpage.
Flake white hue doesn't contain the lead which is considered dangerous. The EU in their wisdom decided to ban flake white or cremnitz white which has now been withdrawn from art shops and from the web and the oil paint maker such as Winsor and Newton and Michael Harding have discontinued their lines in this product.