A preparation of plaster of Paris and glue used as a base for low relief or as a surface for painting.
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Gesso (not sure how to spell it)
In order to paint on PVC canvas you must prep the canvas by gently sanding some of the pvc coating off with a medium grit sandpaper. This will allow the paint to adhere to the PVC. Wipe the canvas clean and allow to dry before priming it. Once the primer is dry you can use acrylic paints to create your master piece.
I don't think you can't make canvas totally waterproof. However, an aqueous coating may be applied to a painting or giclee canvas prints to protect it from smudges, dirt and fading. Canvas printing companies usually have this option. Check the links below.
a Canvas the white board
pablo picasso did not have respect for his women this was what people called the blue period