When an individual mixes purple and orange together (In terms of paint or something similar - to achieve a new colour), that individual should get a muddy brown / gray colour (Depending on the amount of each colour the individual uses).
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A muddy brown color is the color you get when you mix purple and green. To make purple you can mix red and blue, and to make green you can mix yellow and blue. However, when secondary colors like purple and green are mixed together. But it generally creates a brown hue.
I don't know about mocha brown, but to make various shades of brown, you mix complementary colors: red and green, orange and blue, purple and green, purple and yellow, pink and green
You would mix it with yellow, it's complimentary colour. Whenever you want to make the colour brown, just mix it with a complimentary colour. (Purple + Yellow, Red + Green, Orange + Blue.)
I'm not a big fan of olive green but it's a greeny yellow colour a bit like an olive XD
Try purple and red. Mix with yellow and green. The blue will have a slight purple tint but its a blue.