No, the Last Supper didn't hold just men, but there is one woman on the left hand side of Jesus, if you have all ready realized that and don't know who she is and if you didn't realize and are curious to find out, that woman in the Last Supper is Jesus' 2nd disciple- known fairly by the "Apostle of Apostles", and is his wife, Mary Magdalene, if you don't believe that is Mary, and believe that is John, you are sadly mistaken, I was sadly mistaken myself actually because we all (of course) believe there was only men in that painting--but apparently no. If you still have disbelief about the information I just gave you, you are welcome to read about Mary Magdalene on Google, Wikipedia, or some website like that, I am only 13 and I am still discovering new things about Catholicism /:
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The men depicted in The Last Supper are Jesus and His twelve apostles.
Jesus’ garb would have been a far cry from the depiction in da Vinci’s The Last Supper. He wore a tunic (chitōn), which for men normally finished slightly below the knees, not at the ankles. Among men, only the very rich wore long tunics
In the last supper Judas was sitting near Jesus. then only was it possible for him to dip into the same bowl of food.
Jesus attended only one supper, hence the name "last supper." At the last supper, Jesus instituted the Eucharist and laid the foundation for the Catholic Mass. Many other Christians today celebrate this "last supper" on Sunday mornings at church as a means of symbolic reunion with God.
There was not a woman at the Last Supper. The record is below, no woman was present. Jesus had the Last Supper with the 12 apostles.