You can remove dry paint from baseboards by scraping the baseboards lightly. You can also use pain thinner depending on the finish on the baseboards.
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Let it dry well first. When dry a week or so remove it with a wire brush.
As long as you are using a similar type of paint (I expect it is an indoor latex, since baseboards are found indoors) and as long as the existing paint is still in good condition and is not flaking off, then yes, you can paint right over the existing paint. If the paint is in bad condition, you should remove it before repainting.
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Remove the lens. Dip the frame in the bucket of paint of preferred colour. Remove the frame. Watch the paint dry. Place back the lens. Enjoy the swanky new look!
Gently scrape the paint and apply a dry spotter. Apply stain remove to loosen the stain while using an absorbent pad.