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Oh, absolutely! Painting Rust-Oleum over latex is possible, but you'll want to make sure the latex paint is fully cured and clean before applying the Rust-Oleum. Just remember to lightly sand the latex paint and apply a primer before painting with Rust-Oleum for the best results. Just like in painting, it's all about layering and taking your time to create something beautiful.
if it is water based, then water, if it is oil based, mineral spirits
You can paint over latex paint with either an oil or water based enamel paint as long as the surface is dull, clean and rust free. Any bare metal will need to be primed with a primer, either oil based or 100% acrylic Direct-to-metal, prior to top-coating.
It's too hot. Try VHT extreme temp stuff is about as durable as paint gets on a hot surface. You can always aluminize, but it's costly.
The brand name Rustoleum is on paints with several different bases so it's best to read the instructions on the label or the data sheet for the paint to determine the proper solvent used to thin.