Decoupage is the art of glueing paper cutouts onto other objects
Yes you can polcrylic seal over the paper cutouts
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You cannot paint over slightly tacky latex paint with a water based polycyclic finish. You should always wait until the latex paint is thoroughly dry before painting over it.
Wipe the surface with some denatured alcohol on a rag. If the paint melts, it's a latex, if it just cleans the surface it's oil. After cleaning and deglossing by sanding, or if oil based, chemically deglossing, coat the surface with a like product. If it's oil based and you want to change it to oil, apply an oil-based primer as a bridge, then apply a high quality acrylic paint over the primer.
It depends what surface is. Usually you can apply oil based paint if surface is smooth.
Not giving the paint underneath enough time to cure would be one cause, another is the decal is not a quality made vinyl decal, resulting in it bot adhering to the paint underneath.
Yes.