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While I wasn't able to find a specific name associated with the unification of the electromagnetic spectrum, I would suspect that it was James Clerk Maxwell, the man who discovered the link between electricity and magnetism, thus coining the term "electro-magnetic".

The spectrum itself is just a list of the ranges of energy that a photon can be at. By studying visible light we can develop the equations that eventually lead to everything from radio waves to gamma waves.

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Q: Who was the first person who proved visible light is only part of the elctromagnetic spectrum?
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