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Counting the first two versions (XCV 330 and NX-01) Captain James Tiberius Kirk would be third. The third captain of the starship Enterprise is uncertain. If one goes purely by the television series, the first was Captain Jonathan Archer, second was James T Kirk and third was Jean-Luc Picard. But one cannot go purely by the main captains of the TV series, as Captain Pike was in the pilot episode before Kirk, and another captain was alluded to also during the original series of Star Trek.

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15y ago
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14y ago

First is the Captain - Kirk

Second - Spock

Third - Scotty

How I know this; Every time Kirk left the Ship, Scotty is told to 'take the helm'

Fourth - McCoy

Fifth- Uhura

Sixth - Sulu

Seventh - Chekov (He's 17- 18 in the shows)

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In the Original Star Trek the third in command of the USS Enterprise was Lt. Commander Montgomery Scott the Cheif Engineer

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14y ago

Ranked second in command aboard the Starship Enterprise in the Next Generation is Commander William T. Riker.

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14y ago

Mr. Spock (in the original series); Commander Riker (in the Next Generation series)

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Q: Second in command on the starship enterprise?
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