Episode 10 is the earliest I can get w/out actually watching it. On that topic: Technically he did make an appearnce, but it was in his mysterious jutsu thing that was purposely supposed to conceal his face for drama. But an episode where his face is shown yet to air. The bottom half of his face can be seen in the 4th opening.
The first path of Pain that is seen in the anime is in episode 128.
Pain appears in Naruto shippuuden episode 16 in a jutsu.
Naruto fights pain in six episodes. In naruto shippuden episode 163-168.
O think it starts at episode 162 and ends at 167 or 168
Its a whole series of episodes, but the main battle is in episode 167
The fighting starts episode 167 and ends 168.
Episode 163 to Episode 174.
episode 419
Fndndndn
it starts at episode 163
Just watch naruto shippuden until the fight with naruto and pain finishes
Naruto Shippuuden episode 43 can be found on a website called Dailymotion.
Naruto Shippuden Episode 161 shows when he actually uses it in combat against Pain.
Naruto fought pain because pain killed jiraiya.And naruto become the sixth hokage
it starts at episode 163
In naruto shippuden 163 naruto arrives at leaf village to find it destroyed. He begins to fight pain and the episode ends with naruto throwing rasenshuriken at pain.
Naruto Shippuden Episode 114
The battle starts toward the end of episode 163 in Naruto Shippuden and goes until episode 169. In episode 172, He meets Nagato, who has been controlling the six paths of Pain.
Naruto fights pain in 6 episodes which are 163-168. He starts to fight pain in episode 163 and defeats him in 168 if you are just counting the 6 pains that he controls. So far naruto hasn't confronted the real pain in person so the fight is not completely over. 7/15/10
Jiraiya fought pain in episode 130-133
Shippuden 163
Chapters 430 to like 444. The way the chapters are im guessing that it how much is about Naruto vs. Pain.
Just watch naruto shippuden until the fight with naruto and pain finishes
pon
Naruto Shippuuden episode 43 can be found on a website called Dailymotion.
Naruto Shippuden Episode 161 shows when he actually uses it in combat against Pain.