No wurmple can not learn flash
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No, Plusle cannot learn Surf.
No, it cannot learn Rock Smash.
In Pokemon ruby, sapphire, and emerald, Zigzagoon cannot learn the move dig.
Trapinch learns Dig at level 41 in Pokemon Ruby, Sapphire, and Emerald.
In Pokemon Ruby, Sapphire, and Emerald, Nincada can learn Dig at level 45. It can learn Dig at a earlier level by using TM 28.