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This is because there is either more fuel to oxygen; too rich a mixture, or more oxygen to fuel; too lean a mixture. To get the mix precisely correct may be theoretically possible but would lead to a very expensive, complex engine management system as the air being introduced for each fireing of each cylinder would have to be analysed for it's number of oxygen molecules and the number of molecules of petrol matched. Air is more dense in colder weather, leading to more oxygen in each cc3 of air introduced to the cylinder and petrol is not going to be precisely the same throughout either. The aim of engine designers is to get a close match which results in an efficient as possible engine without too high a cost to the end user.

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Q: Why is there incomplete combustion in an internal combustion engine?
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