Yes. Czech Republic has President. The current president of Czech Republic is Vaclav Klaus.
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Edvard Beneš
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Vaclav Klaus is the current president of the Czech Republic.
Miloš Zeman is the President of the Czech Republic in 2014. He became the president on 2013 March 8. He was previously the Prime Minister of the Czech Republic from 1998 July 22 to 2002 July 15.
Miloš Zeman is set to become the third President of the Czech Republic in 2013. He is the first directly elected president in Czech history. He served as the Prime Minister of the Czech Republic from 1998 to 2002. Last president of Czechoslovakia was Václav Havel, until 1993 when Czech and Slovak Republics were established. President of Slovak Republic is Ivan Gašparovič.
Milos Zeman is the current President of the Czech Republic as of October 2013. He makes 2,235,600 Czech koruna per year. That is around $655,926.
Václav Havel
Czech citizen, counterrevolutionary, and eventually president president of Czechoslovakia
If by chief you mean president then the president is Vaclav Klaus.