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Grout was not properly mixed. It most likely mixed with to much water. Your water could be aggressive with a low pH attacking the grout and plaster. Test and adjust. If your pH is below 6.8 and has stabilized there your pool plaster should start to look copper color, aqua color, have black stains which look like graying spots. But once the damage is done you can't undo it.

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Q: What would cause new grout in swimming pool to rub off easly?
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