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Dr M Kanagasabapathy

Asst. Professor in Chemistry

Rajus college, Affiliated to M K University

Rajapalayam (TN) India

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Lead acid battery contains the following

1. Lead PB

2. Lead oxide PbO

3. Sulfuric acid H2SO4

During discharging Pb Oxidizes to Pb 2+ and PbO2 reduces to Pb2+ from Pb 4+

PbO2 + Pb + H2SO4 = 2 PbSO4 + H2O (~ 2.0 V per cell)

During charging the reverse reaction takes place

Pb2+ reduces to lead at cathode and another molecule of Pb2+ oxidizes to PB4+ or PbO2 by reacting with distilled water.

2 Pb(2+) + H2O2 = Pb + PbO2 (> 2.0 V per cell)

The important thing is the voltage for recharging should be slightly higher than the discharging voltage.

During discharging the battery functions as electrochemical cell.

And during charging it becomes an electrolytic cell.

By,

Dr M Kanagasabapathy

Asst. Professor in Chemistry

Rajus college, Affiliated to M K University

Rajapalayam (TN) India

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