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Not very long at all. The baking powder that is in it works two ways. It reacts with the liquid to cause it to rise and with the heat of the oven. Once liquid is added to the dry ingredients, it starts working. It only does this once and if it's not in the oven, it will be sort of like a cake falling when you are baking it. The cake should still rise in the oven, but it will not be as much and possible not evenly.

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Q: How long can an unbaked cake be stored in the refrigerator before baking it?
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